| Portfolio | Name of Minister |
| Prime Minister
Ministry of Personnel, Public Grievances and Pensions
Ministry of Planning
Department of Atomic Energy
Department of Space | Dr. Manmohan Singh |
| Minister of Finance | Shri Pranab Mukherjee |
| Minister of Agriculture
Minister of Food Processing Industries | Shri Sharad Chandra Govindrao Pawar |
| Minister of Defence | Shri A.K. Antony |
| Minister of Home Affairs | Shri Palaniappan Chidambaram |
| Minister of External Affairs | Shri S.M. Krishna |
| Minister of Micro, Small and Medium Enterprises | Shri Virbhadra Singh |
| Minister of Science and Technology
Minister of Earth Sciences | Shri Vilasrao Dagadojirao Deshmukh |
| Minister of Health and Family Welfare | Shri Ghulam Nabi Azad |
| Minister of Power | Shri Sushil Kumar Sambhajirao Shinde |
| Minister of Corporate Affairs | Shri M. Veerappa Moily |
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